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基于最小自由能法的烟火药燃烧产物预测模型 被引量:11

Calculational Model of Pyrotechnical Combustion Products Based on Minimum Free Energy
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摘要 燃烧产物的预测对烟火药的设计非常重要。文中采用最小自由能法原理,建立了烟火药燃烧产物预测模型,使用傅立叶变换红外光谱仪对实际燃烧产物进行了分析。在预测产物与实际燃烧产物对比的基础上,修正了理化参数数据库后,预测结果同实际产物完全相同,验证了模型的合理性。 A model of pyrotechnical combustion products was established based on the principle of minimum free- energy. Actual products was analyzed by FTIR and compared with calculational result. After thermodynamic and physical property data was corrected, two results were identical. This confirmed the rationality of model.
出处 《弹箭与制导学报》 CSCD 北大核心 2006年第1期120-122,共3页 Journal of Projectiles,Rockets,Missiles and Guidance
基金 国防预研基金项目(41305070201)
关键词 最小自由能 烟火药 燃烧产物 预测模型 minimum free energy, pyrotechnical agent, combustion product, ealeulational model
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参考文献3

  • 1R E Williford,T R Armstrong.Chemical and thermal expansion of calcium-doped lanthanum chromite[J].Journal of Solid State Chemistry,2000,149:320.
  • 2Cheynet B,Dall'Aglio M,Garavelli A,et al.Trace elements from fumaroles at volcano island (Italy):rates of transport and a thermochemical model[J].Journal of Volcanology and Geothermal Research,2000,95:273.
  • 3Yaws C L.Thermodynamic and Physical Property Data,Comprehensive Thermodynamic and Physical Property for Hydrocarbons and Organic Chemicals[M].1st ed.Texas:Gulf Publishing Co.Houston,1992.

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