摘要
本文综述了不对称催化环氧化体系的研究进展。重点评述了Ｓｈａｒｐｌｅｓｓ－Ｋａｔ．ｓｕｋｉ不对称环氧化反应的特点、机理、新进展与应用，综合分析了由手性（ｓａｌｅｎ）Ｍｎ（Ⅲ）催化剂对非功能化烯烃所创建的突出成果与应用前景。
The developments of asymmetric catalytic epoxidation systems were reviewed,with emphasis on the inspiring results and promising applications of asymmetric epoxidation of unfunctionalized cis-olefins catalyzed by optical active(salen)Mn(0283)complexes [salen=N,N’-ethylenebis(salicylideneaminato)],as well as the merits、mechanism、new developments and applications of SharplessKatsuki asymmetric epoxidation。
出处
《化学进展》
SCIE
CAS
CSCD
1996年第1期57-78,共22页
Progress in Chemistry
关键词
不对称环氧化
不对称催化
卟吩
非功能化烯烃
asymmetric epoxidation
asymmetric catalysis
chiral salen complex
pornhin
unfunctionalized olefin
allylic alcohol
