摘要
本文通过引入两个共价因子Ｎｔ，Ｎｅ，推导了包含Ｒａｃａｈ参量Ａ的能量矩阵，并用高阶微扰方法推导了ｇ因子计算公式．在此基础上计算了ＺｎＳｅ：Ｃｏ２＋的晶场光谱和顺磁ｇ因子．其理论值与实验结果吻合较好．
In this paper, two covalent factors are introduced. And then, the energy matrices of 3d 3/7 ion in O k(T d) crystal field and the peturbation formulas up to third order for g factor, which include the contribution from Racah parameter A , are derived. In terms of these formulas, We calculate the spectrum and g factor of Co 2+ in ZnSe, the results agree with the experimental finding. For the semiconductor which have stronge covalency, the results show that the contribution from the Racah paramater A to the spectrum and the g shifts can not be neglected.
出处
《四川师范大学学报（自然科学版）》
CAS
CSCD
1996年第2期69-72,共4页
Journal of Sichuan Normal University（Natural Science）
