摘要
研究了Ｆｅ３（ＣＯ）１２／ＺＳＭ－５的制备方法及反应条件对ＣＯ２／Ｈ２合成低碳烯烃反应性能的影响。结果表明，采用该实验室发展的分步回流浸渍法能有效地将Ｆｅ３（ＣＯ）１２负载在ＺＳＭ－５分子筛上。该催化剂在常压下对ＣＯ２／Ｈ２合成低碳烯烃反应有良好的催化性能。
he effects of different preparation methods and reaction conditions on catalytic properties of Fe3 (CO)12/ZSM-5 catalysts for light olefin synthesis from carbon dioxide and hydrogen have been studied. It is found that the Fe3(CO)12/ZSM-5 catalyst which has been prepared by the 'Multiple Reflux-Impregnation-Step' method developed in our laboratory exhibits a very high selectivity for light olefin and give a highly catalytic activity for hydrogenation of carbon dioxide.
出处
《石油化工》
CAS
CSCD
北大核心
1996年第4期267-270,共4页
Petrochemical Technology
基金
国家自然科学基金
关键词
催化剂
低碳烯烃
制备
Fe_3 (CO)_(12)/ZSM-5 catalyst,carbon dioxide hydrogenation,light olefin
