期刊文献+

原位反应增容无机非卤阻燃ABS微观结构研究 被引量:1

Study on Microstructure of Inorganic Halogen-free Flame Retardant ABS Prepared by In-situ Reaction Compatibilization
在线阅读 下载PDF
导出
摘要 利用扫描电镜对原位反应增容技术制备的无机非卤阻燃ABS母粒及材料的界面形态进行了系统研究,考察了无机非卤阻燃剂与ABS树脂间的相容性。结果表明:采用该法制得的无机非卤阻燃ABS材料阻燃剂粒子被基体树脂包覆后均匀地分散在ABS树脂中,很难看出阻燃剂与ABS之间明显的界面,断裂截面显示出韧性断裂的基本特征,无机非卤阻燃剂与ABS良好的相容性是母粒法加工技术和原位反应增容技术共同作用的结果。 A halogen-free flame retardant masterbatch was prepared by in-situ polymerization of a polar vinyl monomer initiated with DCP in ABS matrix, and subsequently blended with Al (OH)3 and Mg(OH)2. This masterbatch was introduced into neat ABS resin to yield a halogen-free flame retardant ABS. SEM revealed that the inorganic particles were well dispersed in matrix. The fractured surface showed a ductile feature.
出处 《中国塑料》 CAS CSCD 北大核心 2006年第1期22-24,共3页 China Plastics
基金 广东省科技攻关项目(2003C33501)
关键词 非卤阻燃ABS 原位反应 微观结构 相容性 halogen-free flame retardant acrylnitrile-butadiene-styrene copolymer in-situ reaction microstructure compatibility
  • 相关文献

参考文献8

  • 1李响,钱立军,孙凌刚,周政懋.阻燃剂的发展及其在阻燃塑料中的应用[J].塑料,2003,32(2):79-83. 被引量:71
  • 2刘岚,冯开才,叶大铿.ABS的卤素-金属氧化物协同阻燃体系[J].高分子材料科学与工程,1998,14(6):82-84. 被引量:3
  • 3Chiu S H, Wang W K. Dynamic Flame Retardancy of Pdypropylene Filled with Ammonium Polyphosphate, Pentaerthritol and Melamine Additives[J]. Polymer, 1998,39(10):1951 -1955.
  • 4Chiu S H, Wang W K. The Dynamic Flammability and Toxicity of Magnesium Hydroxide Filled Intumescent Fire Retardant Polypropylene[ J ]. Journal of Applied Polymer Science,1998,67: 989- 995.
  • 5Liauw C M, Lees G C, Hurst R N, et al. The Effect of Filler Surface Modification on the Mechanical Properties of Aluminum Hydroxide Filled Polypropylene [ J ]. Plastics,Rubber and Composites Processing and Applications, 1995,24: 249-260.
  • 6Liauw C M,Lees G C,Hurst R N,et al. Investigation of the Surface Modification of Aluminum Hydroxide Filler and Optimum Modifier Ebsage Level[J]. Plastics, Rubber and Composites Processing and Applications, 1995,24:211-219.
  • 7刘芳,黄伟,吴小华,林晓丹,贾德民.原位反应增容法制备非卤阻燃ABS[J].塑料工业,2004,32(3):28-29. 被引量:5
  • 8刘芳,黄伟,吴小华,林晓丹,贾德民.正交设计在非卤阻燃ABS制备中的应用[J].塑料,2004,33(5):55-58. 被引量:2

二级参考文献15

  • 1薛恩钰 曾敏修.阻燃科学及应用[M].北京:国防工业出版社,1988.379.
  • 2金良超.正交设计与多指标分析[M].北京:中国铁道出版社,1988..
  • 3奥野孝一.环氧树脂的制备[P].JP 日本公开特许公报, 昭 57—47322.1982.
  • 4[2]S R Owen,J F Harper.Mechanical,microscopical and fire retardant studies of ABS polymers[J].Polymer degradation and Stability,1999,64(3):449-455.
  • 5[3]D Stevanovic,A Lowe,S Kalyanasundaram,et al.Chemical andmechanical properties of vinyl-ester/ABS blends[J].Polymer,2002,43(16):4503-4514.
  • 6[6]Ma Z-L,Zhao M,Hu H-F,et al.Compatibilization of intumescentflame retardant/polypropylene composites based on α-methacrylic acid grafted polypropylene[J].J of Applied Polymer Science, 2002,83(14):3128.
  • 7[7]Ma Z-L,Gao J-G,Niu H-J,et al.Polypropylene-intumescent flame-retardant composites based on meleated polypropylene as a coupling agent[J].J of Applied Polymer Science,2002,85(2):257.
  • 8Baton Rouge, Saadat Hussain. Process of preparing diphenylalkane[P]. US 4929785,1990.
  • 9冯开才,广东塑料,1994年,3期,3页
  • 10欧育湘.阻燃剂--制造,性能及应用[M].北京:兵器工业出版社,1996.6.

共引文献77

同被引文献7

  • 1Youngyoun Ji, Jinhwan Kim, Jin-Young Bae, et al. Study on the thermal stabilization enhancement of ABS:Synergistic effect by triphenyl phosphate and epoxy resin mixtures[ J]. Polymer,2003 (43) :2 249 -2 253.
  • 2Youngyoun Ji,Jinhwan Kim,Jin-Young Bae,et al. Studies on the thermal stabilization enhancement of ABS : Synergistic effect of triphenyl phosphate nanocomposite,epoxy resin, and silane coupling agent mixtures [ J ]. Polymer Degradation and Stability ,2003,79 ( 3 ) :201 - 207.
  • 3Wang Zhengzhou, Wu guosheng, Hu Yuan, et al. Thermal degradation of magnesium hydroxide and red phosphorus flame retardant polyethylene composites [ J ]. Polymer Degradation and Stability ,2002,77 (3) :427 - 434.
  • 4Kunwoo Lee,Kangro Yoona,Jinhwan Kima,et al. Effect of novolac phenol and oligomeric aryl phosphate mixtures on flame retardance enhancement of ABS [ J ]. Polymer Degradation and Stability,2003,81 (3) : 173 - 179.
  • 5洪重奎,金敏善.ABS/PVC/NBR三元共混合金的研究[J].中国塑料,2001,15(8):50-52. 被引量:10
  • 6瞿雄伟,商淑瑞,刘国栋,姬荣琴,张留成.丙烯腈-三元乙丙橡胶-苯乙烯接枝共聚物的合成与表征[J].高分子材料科学与工程,2002,18(5):104-107. 被引量:18
  • 7权英,杨明山,严庆,李瑞俊.阻燃ABS有色工程塑料合金的制备及其性能的研究[J].现代化工,2003,23(7):30-33. 被引量:3

引证文献1

二级引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部