摘要
Reaction of sodium 2,6-di-tert-buty1-4-methylphenolate with CuCl o CuCl2 in THF affords metallic copper and 3,5,3’,5’-tetra-tert-butyl-stilbene4,4’-quinone in good yield.The product was characterized by melting point,elemental analysis,IR,MS and X-ray cerystallography.The molecular structure of the title compound was for the first time elucidated.
Reaction of sodium 2,6 - di - tert - butyl - 4 - methylphenolate with CuC1 o CuC12 in THF affords metallic copper and 3,5,3＇ ,5＇ - tetra - tert - butyl - stilbene - 4,4＇ - quinone in good yield. The product was characterized by melting point, elemental analysis ,IR, MS and X- ray eerystallography. The molecular structure of the title compound was for the first time elucidated.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2006年第2期202-203,共2页
Chemical Research and Application
基金
江苏省青蓝工程(HB2001-27)项目资助
江苏省教育厅基金(04KJD560171)项目资助
关键词
酚
氧化偶联
分子结构
phenol
oxidative Coupling
molecular structure
