摘要
Photoconductive properties of photodiodes based on composites of CuS nanoparticles and Poly[2-methoxy,5- (2'-ethylhexyloxy)-p-phenylenevlnylene] (MEH-PPV) are investigated. By comparing composite devices with different MEH-PPV:CuS weight ratios of l:l (D2-1), 1:1.25 (D2-2), 1:2.5 (132-3) and 1:5 (D2-4), it is found that the device D2 3 exhibited the best performance: the short-circuit current density of 17μA/cm^2 with the light intensity of 16.7mW/cm^2, the highest open-circuit voltage of 0,83 V, and the photosensitivity of 132 at reverse bias of - 1 V. The photosensitivity is improved by a factor of 5 compared with the undoped MEH-PPV device.
Photoconductive properties of photodiodes based on composites of CuS nanoparticles and Poly[2-methoxy,5- (2'-ethylhexyloxy)-p-phenylenevlnylene] (MEH-PPV) are investigated. By comparing composite devices with different MEH-PPV:CuS weight ratios of l:l (D2-1), 1:1.25 (D2-2), 1:2.5 (132-3) and 1:5 (D2-4), it is found that the device D2 3 exhibited the best performance: the short-circuit current density of 17μA/cm^2 with the light intensity of 16.7mW/cm^2, the highest open-circuit voltage of 0,83 V, and the photosensitivity of 132 at reverse bias of - 1 V. The photosensitivity is improved by a factor of 5 compared with the undoped MEH-PPV device.
基金
Supported by Trans-Century Training Program Foundation for the Talents of Natural Science by the State Education Commission, the Key Project of the Ministry of Education of China under Grant No 105041, the National Natural Science Foundation of China under Grant Nos 90401006, 10434030 and 90301004, and the National Key Basic Research and Development Programme of China under Grant No 2003CB314707.