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Pb(Ⅱ)在Nafion修饰电极上的机理研究 (Ⅱ)富集过程中的离子交换和物理扩散 被引量:1

A Study on the Mechanism of Ph(Ⅱ) Action on Nafion Modified Electrodes(Ⅱ) Ion-Exchange and Diffusion during Preconcentration
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摘要 测定Pb(Ⅱ)在Nafion修饰电极上离子交换富集过程中的离子交换系数及物理扩散系数,提出了该过程中,Pb(Ⅱ)在Nafion膜中的浓度分布模型和Pb(Ⅱ)离子交换与扩散模式. A determination was made on ion-exchange coefficient and diffusion coefficient of Pb (Ⅱ) over Nafion modified electrodes during the process of ion-exchange concentration. On this basis,the authors put forward a model of Ph(Ⅱ)concentration distribution over Nafion polymer film and a model of Ph(Ⅱ) ion exchange and diffusion during this process.
出处 《华侨大学学报(自然科学版)》 CAS 1996年第1期14-17,共4页 Journal of Huaqiao University(Natural Science)
基金 华侨大学与日本国岐阜大学共同科学研究协定资助
关键词 离子交换 修饰电极 NAFION膜 Pb(Ⅱ) Nafion ion-exchange
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  • 1Shahinpoor M,Kwang J Kim. Novel Ionic Polymer-metal Composites Equipped with Physically Loaded Particulate Electrodes as Biomimetic Sensors, Actuators and Artificial Muscles[J]. Sensor and Actuators, 2002, 96:125~ 132.
  • 2Sia Nemat Nasser,Jiang Y L. Electromechanical Response of Ionic Poly-metal Composites[J]. Journal of Applied Physics,1999,87(7): 3321~3331.
  • 3扬大智.智能材料与智能系统[M].天津:天津大学出版社,2000.337.
  • 4Shahinpoor M,Kwang J Kim. The Effect of Surface electrode Resistance on the Performance of Ionic Polymer-metal Composite Artificial Muscles[J]. Smart Material and Structures Journal, 2000,9 (4): 543 ~ 551.
  • 5Kwang J Kim, Shahinpoor M. A Novel Method of Manufacturing Three-dimensional Ionic Polymer-metal Composites Biomimetic Sensors, Actuators and Artificial Muscles[J]. Polymer, 2002, 43: 797~802.
  • 6Sia Nemat Nasser. Micromechanics of Actuation of IPMC[J]. Journal of Applied Physics, 2002,92(5):1~21.
  • 7Kucernak A R, Muir B. Analysis of the Electrical and Mechanical Time Response of Solid Polymer-platinum Composite Membranes[J]. Electrochemica Acta, 2001, 46: 1313~1322.
  • 8Shahinpoor M,Kwang J Kim. Ionic Polymer metal Composites[J]. Smart Mater Struct, 2001,10:813~819.
  • 9Bar Cohen Y, Leary S, Shahinpoor M,et al. EAP Actuators for Planetary Applications[J]. Mewport Beach,1999,(3):1~6.
  • 10余海湖,赵愚,姜德生.智能材料与结构的研究及应用[J].武汉理工大学学报,2001,23(11):37-41. 被引量:21

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