摘要
本文采用电化学石英微天平(EQCM)研究了现场监测了摩尔比不同的邻氨基苯甲酸/苯胺混合溶液的共聚膜在不同pH值B-R缓冲溶液中的不同性质和过程。发现溶液中邻氨基苯甲酸的含量和溶液的PH值对苯胺/邻氨基苯甲酸的共聚膜的溶胀/溶解行为均具有很大的影响。
The swelling/dissolution behavior of the (o-anthranilic acid-aniline) copolymers versus solution pH was traced via the EQCM frequency and resistance signals, and its large dependence on F1 was found and discussed, where F1 is defined as the molar fraction of o-anthranilic acid relative to the total amount of the two monomers in the copolymerization solutions.