摘要
研究了不同铜盐对溴代苯酚聚合反应产率的影响，利用Ｔａｆｔ取代基常数作为考察指标，得出∑σ＊＞５．５时，铜（Ⅱ）盐有催化活性，而钢（Ⅰ）盐则无催化活性，并利用ＥＳＲ（ＥｌｅｃｔｒｏｎＳｐｉｎＲｅｓｏｎａｎｃｅ）检测出反应体系中有酚氧自由基的存在．
Studies the copper salt-catalyzed polymerization of 2, 4, 6-tribromophenol with the different copper salt catalysts. Copper(Ⅱ) salt has catalytic activity when Taft substituent constant ∑σ >5. 5, but copper(Ⅰ) salt has no catalytic activity. The phenoxy radical, considered as an intermediate of the reaction, was detected by ESR.
