摘要
The preparation of palladium complex from PdCl2·2H2O and carbosilane dendrimers with pelripheral aminopropyl groups was described. The compound obtained was characterized by IR, H NMR, X-ray photoelectron spectroscopy （XPS） and inductively coupled plasma atomic emission spectrometric （ICP-AES） spectroscopy respectively. The metal complex was employed as catalyst in hydrogenation of organic compounds. The high activity of the complex was probably due to the formation of the coordinatively unsaturated palladium.
The preparation of palladium complex from PdCl2·2H2O and carbosilane dendrimers with pelripheral aminopropyl groups was described. The compound obtained was characterized by IR, H NMR, X-ray photoelectron spectroscopy （XPS） and inductively coupled plasma atomic emission spectrometric （ICP-AES） spectroscopy respectively. The metal complex was employed as catalyst in hydrogenation of organic compounds. The high activity of the complex was probably due to the formation of the coordinatively unsaturated palladium.
基金
We are grateful to the Natural Seience Fondation of Shandong Province for financial support(Project No.Q 2003 B01and Projecet No.Y 2003 B01)
