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Isolation and Characterization of Two New Compounds from Lysimachia Davurica 被引量:2

Isolation and Characterization of Two New Compounds from Lysimachia Davurica
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摘要 Two new saponins named davuricoside H and davuricoside K were isolated from the whole plant of Lysimachia davurica. The structures of davuricoside H and davuricoside K were determined by 1-D and 2-D NMR, MS techniques, and chemical methods to be 3β,16α ,28-trihydroxy-olean-12-en-30-oic acid-3-O-β-D-glucopyranosyl-( 1→2 )- [β-D-glucopyranosyl-( 1 → 4 ) ] -α-L-arabinopyranoside and 3β,16or ,28-trihydroxy-olean-12-en-30-oic acid-3-O-{β-D- glucopyranosyl- ( 1 →2 ) - [β-D-glucopyranosyl- ( 1 →4 ) ] -α-L-arabinopyranosyl } -30-O-β-D-glucopyranosyl-ester. Two new saponins named davuricoside H and davuricoside K were isolated from the whole plant of Lysimachia davurica. The structures of davuricoside H and davuricoside K were determined by 1-D and 2-D NMR, MS techniques, and chemical methods to be 3β,16α ,28-trihydroxy-olean-12-en-30-oic acid-3-O-β-D-glucopyranosyl-( 1→2 )- [β-D-glucopyranosyl-( 1 → 4 ) ] -α-L-arabinopyranoside and 3β,16or ,28-trihydroxy-olean-12-en-30-oic acid-3-O-{β-D- glucopyranosyl- ( 1 →2 ) - [β-D-glucopyranosyl- ( 1 →4 ) ] -α-L-arabinopyranosyl } -30-O-β-D-glucopyranosyl-ester.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2005年第5期549-551,共3页 高等学校化学研究(英文版)
基金 Supported by the National Natural Science Foundation of China(No. 39870085).
关键词 Lysimachia davurica Triterpenoid saponin Davuficoside H Davuricoside K Lysimachia davurica, Triterpenoid saponin, Davuficoside H, Davuricoside K
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  • 1TianJ. K., Xu L. Z., ZouZ. M., et al. , Foreign Med. Sci.( Fascicule of Traditional Chinese Medicine) , 2002, 24 ( 2 ), 80.
  • 2Tian J. K., Zou Z. M., Xu L. Z., et al., Chin. Tradit.Herb. Drugs, 2001, 32 ( 11 ) , 967.
  • 3TianJ. K., Zou Z. M., Xu L. Z., et al. , China J. Chin.Mater. Med. , 2002, 27(4), 283.
  • 4Jia Z. H., Koike K., Ohmoto T., et al., Phytochemistry,1994, 37(5), 1389.

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