摘要
以乙酸铅、丙酸锌、五乙氧基铌、四丙氧基锆和四正丁氧基钛为原料,用溶胶-凝胶法制备了锌铌酸铅-锆钛酸铅(PZN-PZT)凝胶纤维.该纤维经热解、烧结后成为直径约25μm的陶瓷纤维.陶瓷纤维的表面和断面形貌的电子扫描图像显示:该陶瓷纤维均匀致密,呈圆柱形.X射线分析表明:烧结温度影响陶瓷的晶相纯度.当烧结温度高于1250℃时,该陶瓷及陶瓷纤维呈现纯净的钙钛矿晶相.阿基米德法测得陶瓷和陶瓷纤维的密度分别为7.70×103kg/m3和7.80×103kg/m3.对陶瓷含量为63%的PZN-PZT陶瓷纤维/环氧树脂1-3复合材料压电片,测得其机电转换常数kt、压电常数d33和相对介电常数ε分别为:0.65、403pC/N和1300.以溶胶-凝胶法制备的超细粉体为原料烧结成的PZN-PZT陶瓷,其kt、d33和ε分别为0.48、600pC/N和2627.
By using lead acetate, zinc propionate, niobium ethoxide, zirconium propoxide and titanium butoxide as precursors, zinc and niobium modified lead zirconate titanate （PZN-PZT） gel fibers were fabricated by the sol-gel method. Prolyzed and sintered, The PZN-PZT ceramic fibers with a diameter of about 25μm were obtained. The SEM micrographs show that these ceramic fibers are dense and uniform. The X-ray diffraction patterns show that sintering temperatures will affect the crystal structure of PZN-PZT ceramics. When the sintering temperature higher than 1250℃, the sintered ceramics and ceramic fibers have a pure perovskite structure. The densities of the bulk ceramic and ceramic fiber are 7.70 × 103kg/m^3 and 7.80×103kg/m^3, which were measured by Archimedes method. The electromechanical coupling coefficient kt, piezoelectric coefficient d33 and relative permittivity ε of the PZN-PZT fiber/epoxy 1-3 composite disk with 63% fibers loaded are 0.65,403 pC/N and 1300, respectively. The kt, d33 and ε of the PZN-PZT ceramics made from the sol-gel powder are 0.48, 600 pC/N and 2627, respectively.
出处
《无机材料学报》
SCIE
EI
CAS
CSCD
北大核心
2005年第5期1099-1105,共7页
Journal of Inorganic Materials
基金
留学回国人员研究基金([2003]406)江苏工业学院研究基金香港理工大学资助
