摘要
在统计热力学基础之上，运用数学方法导出了不同反相色谱系统中保留值方程系数换算公式如下：ａ′＝ｋ１＋ｋ２ａ＋ｋ３ｘＡ氢ｃ′＝ｊ１＋ｊ２ｃ＋ｊ３ｘＡ氢采用正构烷烃、卤代苯、烷基苯、氯代酚等类型化合物的实验数据，验证了上述公式。本文为不同反相色谱体系保留值的换算奠定了基础。
The following equations for converting coefficient of retention equation in different reversed-phase liquid chromatographic systems are derived mathematically according to statistical thermodynamic theory: a′=k1+k2aα+k3aAH and c′=j1+j2c+j3ξAH Experimental data of alkane,aromatic hydrocarbon and halogenated compounds were adopted to confirm these equations.
出处
《分析测试学报》
CAS
CSCD
1996年第2期49-53,共5页
Journal of Instrumental Analysis
关键词
反相色谱系统
保留值方程系数
Different reversed-phase chromatographic system.
