摘要
本文报道了一系列多核Mo(W)-Cu(Ag)-S簇合物的低热固相合成,发现硫代钼(钨)酸铵与铜(银)的成簇规律主要与团相反应温度密切相关,提出了四核至七核Mo(W)-Cu(Ag)-S簇合物的可能成簇机理.
In this paper, solid state synthesis of a series of Mo (W) - Cu (Ag) - S cluster compounds at low heating temperatures has been reported. It has been found that the regularity of cluster formation of thiomolybdate (or thiotungstate) with copper (or silver) is closely relevant to the solid state reaction temperatures. The possible mechanism of cluster formation of Mo(W) -Cu(Ag) - S cluster compounds with nuclearity from four to seven has been suggested.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1996年第5期461-467,共7页
Acta Chimica Sinica
基金
江苏省教育委员会自然科学基金资助课题
