N，N＇－二（乙酰芳香环）－穴醚［2，2］的合成

The Syntheses of N,N'-Bis(aroylmethyl)-1,10-diaza-4,7,13,16-tetraoxacyclooctadecane

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摘要Ｎ，Ｎ＇－二（乙酰芳香环）－穴醚［２，２］的合成余江，许振华，徐光宪（北京大学化学与分子工程学院，稀土材料化学及应用国家重点实验室，北京，１００８７１）关键词大环，穴醚［２，２］，ＨＴＴＡ穴醚（Ｃｒｙｐｔａｎｄ）是含有Ｏ及Ｎ和Ｓ等杂原子的多聚大环化合... Two new kinds of organic macrocycle compounds were synthesized with different methods:N,N'-bis( a- phenacyl)-1,10-diaza-4,7,13,16-tetraoxacyclooctadecane(Ⅱ) and N,N'-bis(ω-acetothienone)-1,10-diaza-4,7, 13,16-tetraoxacyclooctadecane(Ⅱ).The fluorescent characteristics of compound Ⅱis better than that of traditional fluorescent ligand of a-thenoyltrifluoroacetone( HTTA).The probable reaction process in our work is also discussed.

作者余江许振华徐光宪

机构地区北京大学化学与分子工程学院

出处《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1996年第5期750-752,共3页 Chemical Journal of Chinese Universities

基金国家自然科学基金

关键词穴醚 HTTA 乙酰芳香环荧光材料 Macrocycle,Cryptand[ 2,2],HTTA

分类号 O626.5 [理学—有机化学] O657.3 [理学—分析化学]

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高等学校化学学报

1996年第5期

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N，N＇－二（乙酰芳香环）－穴醚［2，2］的合成

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