摘要
冠醚DPDB-18-C-6与钾显色反应的分光光度法研究黄青瑜,营豫梅,谢明贵(四川联合大学化学系成都610064)关键词钾,二苦胺基二苯并-18-冠-6,分光光度法目前碱金属的光度测定,较为广泛的是借助阴离子染料生成三元配合物的显色方法[1-2]。近...
The colour reaction of cis-dipicryldibenzo-18-crown-6 with potassium in the medium of pH 8.5 was studied. The maximum absorption of the complex is at 460nm. Following Beer's law for potassiumis in the range of 0-8.0μg/5. 4mL The apparent molar absorptivity at 460nm is 9.4×10 ̄3L· mol ̄(-1)·cm ̄(-1) .The molar ratio of potassium to the reagent in the complex is 1: 1.
出处
《化学研究与应用》
CAS
CSCD
1996年第2期283-285,共3页
Chemical Research and Application
关键词
钾
分光光度法
冠醚
potassium, cis-dipicryldibenzo-18-crown-6, spectrophotometry