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含高碳糖片断的氨基醇及水解产物的波谱分析 被引量：3

Structure Elucidation of A Higher Carbon Sugar-Derived Amino Alcohol and Its Hydrolysate by NMR
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摘要 利用C10高碳糖合成了具有潜在生物活性的含有高碳糖结构片断的氨基醇,检测了该氨基醇及其水解产物的1H、13CNMR图谱,确证了该类化合物的结构,通过1H1HCOSY,HMQC,HMBC等2DNMR技术对其水解产物的1H和13CNMR数据进行了全归属和较详细的解析. An amino alcohol and its hydrolysate, which are potential glycosidase inhibitors, were synthesized from C10 higher carbon sugar. The structures of these novel higher carbon sugar-derived compounds were elucidated by NMR. The ^1H and ^13C chemical shifts of the hydrolysate of the amino alcohol were completely assigned by 2D NMR techniques including ^H-^H COSY, HMQC and HMBC.
作者 邹大鹏 朱卫国 刘宏民
机构地区 郑州大学化学系
出处 《波谱学杂志》 CAS CSCD 北大核心 2005年第3期277-283,共7页 Chinese Journal of Magnetic Resonance
基金 国家自然科学基金资助项目(20272054).
关键词 NMR 归属 2DNMR 高碳糖 氨基醇 NMR, higher carbon sugar, amino alcohol, chemical shift assignment, hydrolysis
分类号 O641 [理学—物理化学]
  • 相关文献

参考文献8

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共引文献5

同被引文献28

  • 1李波,许时婴.气相色谱法测定多糖中的糖醛酸[J].色谱,2004,22(5):560-560. 被引量：34
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  • 4刘丰五,张京玉,刘宏民,宋小平.三种缩水蔗糖衍生物的NMR研究及结构确证[J].波谱学杂志,2005,22(2):149-154. 被引量：4
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波谱学杂志
2005年 第3期

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