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The Effect of Non-Framework Aluminum on the Stability and Activity of REY Zeolite

The Effect of Non-Framework Aluminum on the Stability and Activity of REY Zeolite
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摘要 The present study is focused on the influence of a routine step, washing, following the preparation of calcined rare earth exchanged Y zeolite, on its hydrothermal stability. The hydrothermal stability of REY products, which were washed by different reagents, was observed and characterized by XRD, ICP, NMR, etc. The results reveal that the amount and the chemical type of the acidic media used for washing can significantly influence the content of remaining non-framework aluminum (NFA) and consequently further affect the hydrothermal stability of the washed REY products. The content of remaining non-framework aluminum can be well correlated with the crystallinity of REY products. The present study is focused on the influence of a routine step, washing, following the preparation of calcined rare earth exchanged Y zeolite, on its hydrothermal stability. The hydrothermal stability of REY products, which were washed by different reagents, was observed and characterized by XRD, ICP, NMR, etc. The results reveal that the amount and the chemical type of the acidic media used for washing can significantly influence the content of remaining non-framework aluminum (NFA) and consequently further affect the hydrothermal stability of the washed REY products. The content of remaining non-framework aluminum can be well correlated with the crystallinity of REY products.
出处 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2005年第2期47-51,共5页 中国炼油与石油化工(英文版)
关键词 rear earth Y zeolite hydrothermal stability non-framework aluminum 沸石 稀土元素 催化剂 稳定性 天然气
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  • 1金庆华,物理学报,1991年,40卷,1371页

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