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高铁酸钾作为贮备电池电极材料的研究 被引量:1

Study on Reserve Battery of Ferrate as an Electrode Material
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摘要 以电解法制得的高纯度K2F eO4固体为正极,锌箔或铝箔为负极制成碱性实验电池.通过对Zn-K2F eO4和A l-K2F eO4电池在不同负载下的恒阻放电测试,研究了高铁酸钾电池的电化学性能.结果表明,A l-K2F eO4电池表现出比Zn-K2F eO4电池更为优越的放电性能.基于高铁酸钾在溶液里的不稳定性,提出用A l-K2F eO4电池做贮备电池,并研究其在不同负载、不同温度下的恒阻放电性能及电池的激活时间. A type of alkaline battery composed of super-iron(K2FeO4) anode and metal cathode (Zn or Al) is developed. The electrochemical properties of Zn-K2FeO4 battery and Al-K2FeO4 battery are studied by testing of their discharge capacity at different loads. The experimental results indicate that the Al-K2FeO4 battery shows good discharge properties compared with the Zn-K2FeO4 battery. Owing to instability of K2FeO4 in the solution, Al-K2FeO4 battery as reserve battery is introduced. The electrochemical properties of Al-K2FeO4 reserve battery are studied by testing of their discharge capacity at different loads and temperatures ,by testing of their activating time at different temperatures.
机构地区 郑州大学化学系
出处 《郑州大学学报(理学版)》 CAS 2005年第3期70-74,共5页 Journal of Zhengzhou University:Natural Science Edition
基金 国家自然科学基金资助项目 编号20376077
关键词 高铁电池 放电容量 激活时间 super-iron battery discharge capacity activating time
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