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钛钨杂多配合物的合成与表征

Synthesis and Characterization of Heteropoly Ti-W Complexes
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摘要 首次合成了杂多配合物K2[(C2H5)4N]2[TiW5O19].5H2O和K2[(C2H5)4N]2[(TiO2)W5O18].5H2O,配合物通过IR,UV,TG-DTA,摩尔电导,X射线粉末衍射进行了表征.结果表明[TiW5O19]4-具有L indqvist-Aronsson结构. Two heteropoly complexes K2[(C2H5)4N]2[TiW5O019]·5H2O和K2[(C2H5)4N]2[(TiO2)W5O18]·5H2O were synthesized for the first time. These complexes were characterized by elemental analysis, IR, UV, XRD, TG-DTA and molar conductance; It is deduced that [ TiW5O19]^4- is of Lindqvist - Aronsson structure.
出处 《化学研究》 CAS 2005年第3期10-12,16,共4页 Chemical Research
基金 国家自然科学基金资助项目(40301050)
关键词 钛钨配合物 杂多酸 Lindqvist-Aronsson型 tungstotitanate complex heteropoly acid Lindqvist-Aronsson structure
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