摘要
首次合成了杂多配合物K2[(C2H5)4N]2[TiW5O19].5H2O和K2[(C2H5)4N]2[(TiO2)W5O18].5H2O,配合物通过IR,UV,TG-DTA,摩尔电导,X射线粉末衍射进行了表征.结果表明[TiW5O19]4-具有L indqvist-Aronsson结构.
Two heteropoly complexes K2[(C2H5)4N]2[TiW5O019]·5H2O和K2[(C2H5)4N]2[(TiO2)W5O18]·5H2O were synthesized for the first time. These complexes were characterized by elemental analysis, IR, UV, XRD, TG-DTA and molar conductance; It is deduced that [ TiW5O19]^4- is of Lindqvist - Aronsson structure.
出处
《化学研究》
CAS
2005年第3期10-12,16,共4页
Chemical Research
基金
国家自然科学基金资助项目(40301050)