摘要
Compound Zn(phen)3BDA (1) (BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disul- fonate, phen= 1,10-phenanthroline) composes of the anion part (racemic-(R,S)-6,6′-dibromo-2,2′-dimethoxy-1,1′- binaphthylene-4,4′-disulfonate ) and the cation part which consists of a racemic octahedrally coordinated zinc center defined six nitrogen atoms from three phen rings to form an inorganic chirality that can be resolution by chiral organic ligand, the 3D framework was formed through the strong H-bonding interaction between sulfonate and water. CCDC: 277924.
Compound [Zn （phen）3] [BDA] （1） （BDA =6,6＇ -dibromo-2,2＇ -dimethoxy- 1,1＇ -binaphthylene-4,4＇ -disulfonate, phen= 1,10-phenanthroline） composes of the anion part （racemic-（R,S）-6,6＇-dibromo-2,2＇-dimethoxy-1,1＇-binaphthylene-4,4＇-disulfonate ） and the cation part which consists of a racemie oetahedrally coordinated zinc center defined six nitrogen atoms from three phen rings to form an inorganic chirality that can be resolution by chiral organic ligand, the 3D framework was formed through the strong H-bonding interaction between sulfonate and water. CCDC： 277924.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2005年第9期1437-1438,1280,共2页
Chinese Journal of Inorganic Chemistry
基金
973项目(No.G2000077500)资助项目
