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Ti^(3+)离子掺杂浓度与Ti:Al_2O_3晶体的光谱畸变 被引量:1

Concentration dependent spectral distortion of Ti: A1_2O_3 crystals
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摘要 通过室温下掺杂浓度为0.03~0.45Wt-%范围的Ti:Al2O3晶体的偏振激发光谱,荧光光谱和吸收光谱的测量,从实验上确信,Ti3+在Al2O3基质晶体中不易形成Ti3+离子对。并且发现,随着Ti3+离子掺杂浓度的提高,偏振激发光谱发生了(l)肩/峰强度比增加和(2)长波展宽现象,而相应波段的吸收光谱却未发现这种浓度效应导致的线型畸变。 Concentration-dependent polarzed excitation,fluorescence and absorption spectra of Ti:Al2o3 crystals were measured at room temperature with the Ti3+ ion doped levels from 0.03 wt-% to 0.45 wt-%. Line shape distortion in polarized excitation spectra, indicated as the increasing of the intensity ratio of the shoulder to Peak and spectral broadering at longer wavelength side,were found as the Ti3+ ion concentration increased, whereas such phenomena did not emerge in the polarized absorption spectra at the same band.It is experimentally convinced that no Ti3+ ion pairs were formed even for the highestly doped sample in our experiment.
出处 《中国激光》 EI CAS CSCD 北大核心 1995年第5期369-372,共4页 Chinese Journal of Lasers
关键词 激光光谱 钛离子 掺杂 Ti:Al2O3晶体 光谱畸变 Ti:Al_2o_3crystal spectroscopy
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参考文献2

  • 1邓佩珍,Tech Digest of CLEO’94,1994年
  • 2刘建华,中国激光.A,1994年,21卷,7期,576页

同被引文献11

  • 1李宋贤,陈建中,董美斌,俞贤椿,涂朝阳,吴伯昌,李文俊,王贻祥,钟陈营.可调谐激光材料-掺杂铝酸铍单晶的生长及其光谱特性[J].福州大学学报(自然科学版),1995,23(6):87-91. 被引量:4
  • 2章佶,孙真荣,王祖赓,司继良,王静雅,杭寅,徐军.温梯法生长的Ti:Al_2O_3晶体的光谱分析[J].人工晶体学报,2005,34(4):657-660. 被引量:2
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  • 5Liu J, Deng P, Gan F. Concentration effect on fluorescent characteristics of Ti:Al2O3 crystal [J]. Optical Materials, 1995, 4(6) : 781-785.
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