摘要
合成了两种新型的固体配合物,其组成为K(BrB15C5)X(X=NCS ̄-或Pic ̄-).钾(Ⅰ)离子不仅能与4’-溴苯并-15-冠-5形成常见的1:2夹心式配合物,而且还能生成稳定的1:1型(M:L)固体配合物.
Two novel solid complexes of 4’-bromobenzo-15-crown-5 with potassium thio-cyanate and potassium picrate respectively, having composition of K(BrB15C5)X(X=NCS ̄-or Pic ̄-),have been synthesized and characterized by elemental analysis, infrared spectra,X-ray powder diffraction, molar conductance and solubility measurements. The results re-vealed the formation of 1:1(M:L)type complexes.
出处
《应用化学》
CAS
CSCD
北大核心
1995年第1期73-76,共4页
Chinese Journal of Applied Chemistry
基金
甘肃省中青年科技基金资助项目
关键词
硫氰化钾
苦味酸钾
配合物
合成
冠醚
bromobenzo-15-crown-5-potassium thiocyanate,potassium picrate ,complex,syn-thesis