摘要
本文合成了１，３－双（苯基亚砜）丙烷，１，４双（苯基亚砜）丁烷与１，１０－菲罗啉，２，２’－联吡啶的铕（Ⅲ）配合物，并通过元素分析、红外光谱、紫外光谱、摩尔电导和热分析对该系列配合物进行了表征，并测量和分析了有关五个配合物的荧光光谱．
The mixing-ligand complexes of curopium(Ⅲ) with 1,3-bis(phenylsulfinyl) propane (bphsp), 1,4-bis(phenylsulfinyl)butanc(b and 1,10--phenanthroline(phen), 2,2'-bipyridyl(bipy) have been synthesized and characterized by clemental analysis, spectra(IR,UV-visible), conductance and thermal decomposition data. The solid fluorescence spectra of five curopium complexes of bphsp (or bphsb) and phen(or bipy) were measured at room temperature.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1995年第2期140-146,共7页
Chinese Journal of Inorganic Chemistry
关键词
铕
苯基亚砜
丙烷
菲罗啉
荧光谱
europium(Ⅲ) complex 1,3-bis(phenylsulfinyl)propane 1.4-bis(phenylsulfinyl)butane 1,10-phenanthroline 2,2'-bipyridyl fluoresceuce spectrum
