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过热现象的动力学──液体过热亚稳态研究之一 被引量:3

KINETIC STUDIES ON THE SUPERHEATING PHENOMENA OF LIQUIDS ──STUDIES ON THE METASTABLE STATE OFSUPERHEATED LIQUIDS (I )
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摘要 将均相成核动力学理论应用于液体,得出液体内部形成临界气泡的均相成核速率表达式.使用液滴技术装置测量了环戊烷、正己烷等8种二元混合物的过热极限。并根据动力学理论作了预测,对于多数体系,二者符合较好, The expression of homogeneous nucleation of critical bubbles formed in the superheated binary liquid mixtures was obtained by means of the theory of homogeneous nucleation.The superheats of eight binary liquid mixtures about cyclopentane and he-cane etc. were measuredby the drop-technical apparatus and predicted by the kinetic theory. For most of the systems, theywere agree well.
出处 《天津大学学报》 EI CAS CSCD 1995年第1期89-95,共7页 Journal of Tianjin University(Science and Technology)
基金 国家自然科学基金
关键词 化学动力学 亚稳态 均相成核 过热液体 chemical kinetics, metastable state, homogeneous nucleation, superheated liquids
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同被引文献13

  • 1张红星,林贵平,丁汀,邵兴国,R.G.Sudakov,Y.F.Maidanik.环路热管启动特性的实验研究[J].中国科学(E辑),2005,35(1):17-30. 被引量:26
  • 2曾丹苓.汽-液相变中成核的热力学理论[J].重庆大学学报(自然科学版),1995,18(2):1-8. 被引量:4
  • 3孙良锋,史宇文,刘俊吉,宋世谟.液体过热亚稳态研究(Ⅱ)──过热现象热力学[J].天津大学学报,1996,29(1):30-37. 被引量:4
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