摘要
利用内循环式无梯度反应器进行了BASFK_(8-11)催化剂CO变换反应本征动力学实验.在温度390~430℃,压力0.1~2.0MPa范围内,CO变换反应动力学与幂函数模型和Lang-muirl-Hinshelwood表面反应模型都有较好吻合.实验得到的反应速率方程分别为:
The intrinsic- kinetics experiments of CO shift reaction had been carried out in a internal-recycle gradentless reactor.Over the range of temperature 320~430℃ and pressure 0.1~2.0 MPa,powermodel and Langmuir-Hinsheiwood surface reaction model are both suitdble for CO shift reaction kinetics,and the rate expressions are respectively as following:
出处
《沈阳化工学院学报》
1995年第4期241-246,共6页
Journal of Shenyang Institute of Chemical Technolgy
关键词
动力学方程
变换反应
一氧化碳
催化剂
intrinsic-kinetics equation
CO shift reaction
K_(8-11) catalyst