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磁场对正丁醇与乙酸酯化反应的影响 被引量:4

EFFECT OF MAGNETIC FIELD ON THE ESTERIFACATION OF n-BUTYL ALCOHOL AND ACETIC ACID
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摘要 研究发现在0.3T磁场强度下乙酸与正丁醇混合酯的生成量最高,正丁醇的粘度和表面张力的下降率最大。IR显示经磁场处理后,正丁醇的羟基伸缩振动吸收峰变窄,表明,磁场能够降低体系内分子间的氢键缔合,增强醇与酸的反应活性。 Under the condition of 0.3T magnetic field intensity,the product of the esterformed by mixing,n-butyl alcohol with acetic acid in equal molar ratio is the highest and thedecreasion of the viscosity and the surface tension of the processed,n-butyl alcohol is thebiggest.IR also shows that the stretching and vibrating absorption of hydroxyl in the pro-cessed n-butyl alcohol narrows. The results prove that the magnetic field can decrease aggre-gation degree of hydroxyl bond between molecules and increase the reacting activity of n-butyl alcohol and acetic acid.
机构地区 宁夏大学化学系
出处 《宁夏大学学报(自然科学版)》 CAS 1995年第3期59-62,共4页 Journal of Ningxia University(Natural Science Edition)
关键词 磁场 正丁醇 乙酸 酯化反应 乙酸正丁酯 magnetic field n-butyl alcohol esterification hydroxyl bond
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