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外型-2-莰基-β-羟乙基醚的合成与应用 被引量:1

SYNTHESIS AND APPLICATION OF EXO-2-CAMPHANYL-β-HYDROXYETHYL ETHER
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摘要 通过莰烯与乙二醇的加成醚化合成可用以配制多种香型香精的外型-2-莰基-β-羟乙基醚;利用IR、NMR、气相色谱等手段确定产物的结构及纯度;探索了反应条件对产率的影响;进行了该产品的试生产与应用。 Exo-2-camphanyl β-hydroxyethyl ether was prepared by addition reaction of ethylene glycol andcamphene for use as perfume material.The structure of the product was confirmed by  ̄1H NMR and IRspectra and purity determined by GC. The reaction conditions were studied and trial production and applica-tion of the product were carried out.
机构地区 南京林业大学
出处 《林产化学与工业》 EI CAS CSCD 北大核心 1995年第1期25-28,共4页 Chemistry and Industry of Forest Products
关键词 莰基 羟乙基醚 莰烯 醚化 香料 合成 植物香料 Exo-2-camphanylβ-hydroxyethyl ether Camphene Etherification Perftume
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  • 1钟平,张翘楚.冰片基羟烷基醚的合成与酯化[J].林产化学与工业,1993,13(4):311-315. 被引量:3
  • 2Edwin S. Paint stripping composition and methods [P]. 1997-01-28.
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  • 7萧树德,陈欣权,周萍,等.分子催化萜烯烷氧基化反应的研究I:异莰基烷基醚的合成[J].化学学报,1988,46(7):693-696.
  • 8沈奔,陈庆之,李允隆,等.丝光沸石催化的单萜烯和脂肪醇加成反应的研究[J].化学通讯,1986(4):46-51.
  • 9Kunio Ogasawara, Takahiko Taniguchi. Novel method of catalytic and reductive removal of allyl protective group from N - allyl- amines, N-allylcarboxamides or allyl ethers: PCT Int. WO, 9924381 [ P]. 1999 -05 - 14.
  • 10Yasuhisa Tahira, Yoshihiko Lmanaka. Preparation of tetrabromo- bisphenol bisallyl ethers as fire retardants for themoplatic resins: JP. 1029957 F P1. 1998 - 02 - 03.

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