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缩水甘油硝酸酯的一锅法合成(英文) 被引量：7

One-pot Synthesis of Glycidyl Nitrate
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摘要 环氧氯丙烷滴加到35%的稀硝酸中,于20℃左右进行开环反应,然后用氢氧化钠溶液进行关环反应,得到缩水甘油硝酸酯,得率为60%。用FTIR,1HNMR,13CNMR和元素分析对产物进行了结构表征。 A mild, low cost synthetic method of glycidyl nitrate is developed via so called one-pot procedure. Epichlorohydrin added dropwise to the dilute nitric acid （35wt%） resulted in ring-opening reaction at about 20℃, Ring-closing occurred then by the addition of aqueous sodium hydroxide. Glycidyl nitrate was obtained in moderate yield （60%） and its structure was characterized by Fourier transform infrared spectroscopy, hydrogen and carbon nuclear magnetic resonance and elemental analysis.
作者 邱少君 甘孝贤 樊慧庆
机构地区 西北工业大学材料学院 西安近代化学研究所
出处 《含能材料》 EI CAS CSCD 2005年第4期211-213,共3页 Chinese Journal of Energetic Materials
关键词 有机化学 含能材料 合成 缩水甘油硝酸酯 一锅法 缩水甘油 硝酸酯 一锅法合成 ^1HNMR 氢氧化钠溶液 organic chemistry energetic material synthesis glycidyl nitrate one-pot synthesis
分类号 TQ564 [化学工程—炸药化工]
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参考文献11

  • 1Desai H J, Lewis C T, Millar R W, et al. Synthesis of narrow molecular weight α, ω-hydroxy telechelic poly( Glycidyl Nitrate) and estimation of theroretical heat of explosion [ J]. Polymer, 1996, 37 ( 15 ) :3471 - 3476.
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含能材料
2005年 第4期

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