摘要
二茂铁甲烷,2,2-双二茂铁丙烷,2,2-双二茂铁基丁烷,2,2-双二茂铁基戊烷与乙酸酐、丙酸酐、正丁酸酐通过傅氏酰基化反应生成一系列双二茂铁基烷的酰化衍生物,再经LiAlH4还原得到318个相应的α-羟基双二茂铁烷衍生物。文中并对它们的红外光谱和1H NMR谱性质进行了研究。
A series of acyl derivatives of 2,2-bis-ferrocenylalkanes have been prepared from 2,2-bis -lerrocenylakanes (i .e. bisferrocenyl methane, 2, 2-bisferrocenylpropane, 2, 2-bis-ferroce-nylbutane and 2, 2-bisferrocenylpentane) and acid anhydrides (i.e.acetic- propionic-,n-buty-ric anhydride) by Friedel-Crafts acylation. The ketones were reduced to the correspondingα-hydroxyalkyl derivatives of 2, 2-bisferrocenylalkanes with LiAlH_4·Eighteen α-hydroxya-lkyl and di-(α-hydroxyalkyl)derivatives have been synthesized. The synthesis and charac-teristies of IR and ~1HNMR spectra of the compounds have been discussed.
出处
《应用化学》
CAS
CSCD
北大核心
1989年第3期15-20,共6页
Chinese Journal of Applied Chemistry
基金
中国科学院科学基金
关键词
双二茂铁烷
酰化衍生物
还原反应
Bisferrocenyl methane
2,2-Bisferrocenyl propane
2,2-Bisferrocenyl butane
2,2-Bisferrocenyl pentane
Friedel-Crafes acylation reaction
α-hydroxyalkyl derivetivs
Reduction
