摘要
采用苯胺的等离子体聚合法，得到致密度高、化学稳定性好的自支撑膜。ＩＲ光谱和导电性研究表明，它与化学法聚合得到的聚苯胺有明显不同的结构和特性，而且研究结果提示用此方法可得到中红外区的红外吸收材料。鉴于等离子体聚合产物大多是非结晶的无定形结构，我们通过ＳＥＭ和ＨＥＥＤ研究发现，该聚合产物有单晶存在，这对等离子体聚合的理论和实验研究有着积极的意义。
Two kinds of free standing films with properties of compact textrue and good chemical stability are obtained using plasma technique. Studies on IR spectrum and conductivity show that their structures and properties are far different from the polyaniline polymerized by chemical or electrochemical methods. We are convinced that plasma polymerization is and effective way to get the I.R.absorption material. It is found that there exists crystalline structure in the film from SEM and HEED studies.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
1995年第1期69-73,共5页
Polymer Materials Science & Engineering
基金
国防科工委资助
国家自然科学基金
关键词
苯胺
等离子体聚合
薄膜材料
s: aniline, plasma polymerization, IR absorption material, SEM and HEED,monocrystal
