摘要
合成了ＵＯ_２（ＰＭＢＰ）_２ＨＭＰＡ（ＰＭＢＰ＝１－苯基－３－甲基－４－苯甲酰基－吡唑啉酮－５，ＨＭＰＡ＝六甲基磷酰胺），测定了该配合物的元素组成、红外光语、质子核磁共振谱及晶体结构。该晶体属于单斜晶系，空间群为Ｐ２_１，ａ＝１．１４６８（５）ｎｍ，ｂ＝１．４７７７（２）ｎｍ，ｃ＝１．４０５６（６）ｎｍ，β＝１００．９１（４）°，Ｖ＝２．３３８９ｎｍ￣３，Ｄ_ｃ＝１．４３ｇ／ｃｍ￣３，Ｚ＝２，Ｆ（０００）＝９７９．８５。在配合物中，Ｕ原子采用七配位，其配位多面体为扭曲的五角双锥。
The complex UO2(PMBP)2 HMPA was synthesized, where PMBP=1-phehyl-3-methyl-4-benzoyl-pyrazolone-5 and HMPA=hexamethylphosphoramide. The reaction product has been characterized by elemental analyses, infrared spectra and 1H NMR.The singal-crystal Xray determination shows that the crystal belongs to a monoclinic system, space group is P21 with a=1. 1468 (5)nm. b=1.4777 (2) nm. c=1.4056 (6) nm,β=100.91 (4)°,v=2.3389nm3,Dc=1.43g/cm3, Z=2, the finial R=0.0675. The coordination polyhedron is a pentagonal bipyramid in which the uranium atom is seven-coordinated and the almost linear uranyl group is perpendicular to its equatorial plane.
出处
《福建师范大学学报（自然科学版）》
CAS
CSCD
1995年第1期53-59,共7页
Journal of Fujian Normal University：Natural Science Edition
关键词
铀酰配合物
合成
波谱
晶体结构
uranyl complex
synthesis
spectra
crystal structure
