摘要
用热分析法对硫磺法合成的高粘度聚苯硫醚(PPS)的结晶行为和热裂解行为进行了初步探讨,并与硫化钠法PPS进行了对比。结果表明:杂质的存在对硫磺法PPS的交联结构,热稳定性和结晶行为都有不同程度的影响。
This paper reports preliminary results of the crystallization and the thermal degradationbChavior of high viscosity polypbenylene sulfide ( PPS ) of the sulfur method by thermoanalysis.The results are compared with PPS of the Na_2S method,showing that the crosslinking structure,the thermal stability and the crystalline behavior of PPS of the sulfur method are affected by theimpurity.
出处
《中山大学学报(自然科学版)》
CAS
CSCD
1995年第4期52-58,共7页
Acta Scientiarum Naturalium Universitatis Sunyatseni
关键词
聚苯硫醚
高粘度
结晶行为
硫磺法
热解行为
Polyphenylene sulfide,high viscosity.crystallization behavior,thermal degradationbehavior,crosslinking*