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超临界流体的地质意义 被引量:11

Geological applications of supercritical fluids
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摘要 超临界流体具有一系列特殊性质,如,临界发散性、“临界乳光”、强氧化性、可变的介电常数、较强的溶解性等。地球深部超临界流体的存在不仅影响岩石的性质,而且对地质构造演化有重要的意义;超临界流体为油气的形成提供物质和能量,同时又是热液成矿过程中元素迁移、聚集和矿石矿物赋存空间形成的重要因素;地质构造演化与超临界流体密不可分;超临界流体对地震孕育及岩浆的产生和喷发有重要影响;超临界流体技术(超临界萃取、超临界水氧化等)不但能最大限度地回收有价值的矿物,而且能有效处理“三废”。 The “critical divergence”, “critical opalescence”, intensive oxidation, alterable dielectric constant, extraordinary solvating power and structure character of supercritical fluids are reviewed,and geological applications of supercritical fluids are discussed. The macrocosmic properties of supercritical fluids are tightly concerned with microscopic structure. Supercritical fluids are an important factor in many geological processes. Supercritical fluids play an important role in the processes of fluid-rock reaction and tectonics evolution, participate reaction and provide energy for it in the formation of oil and gas, are profit to migration and enrichment of elements in hydrothermal formation of ore deposits, and greatly affect on generations of seism and magma. Supercritical techniques (supercritical extraction and supercritical water oxidation) can improve recovery ratio of ore and dispose efficiently different kinds of wastes. It was proposed that further work would be done in the fields of supercritical reaction, investigation of deep-earth processes and development of supercritical techniques in environmental geology.
出处 《西北地质》 CAS CSCD 2005年第2期49-53,共5页 Northwestern Geology
基金 国家自然科学基金(批准号12099040) 中科院兰州地质所知识创新基金项目(2003-19-DJG)
关键词 超临界流体 地质构造演化 成矿作用 环境地质 supercritical fluids tectonic evolution metallization environmental geology
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  • 1胡英.近代化工热力学[M].上海:上海科技文献出版社,1993..
  • 2谢洪森.地球深部物质科学导论[M].北京:科学出版社,1997..
  • 3Matyn Poliakoff,Peter King,Phenomenal fluids[J].Nature,2001,412:125.
  • 4Mauro Boero,Kiyoyuki Terakura,Tamio Ikeshoji,et al.Hydrogen Bonding and dipolar moment of water at supercritical conditions: A first-principles molecular dynamics study [J].Physical review letters,2000,85(15): 3245-3248.
  • 5葛良胜,郭晓东,邹依林.试论地球内部流体与地质作用——现代地质科学研究思考[J].地球科学进展,1998,13(2):129-139. 被引量:13
  • 6苏根利,谢鸿森,丁东业,张月明,郭捷.超临界水的物理化学性质及意义[J].地质地球化学,1998,26(2):83-89. 被引量:29
  • 7朱自强.超临界流体技术原理和应用[M].北京:化学工业出版社,2001..
  • 8戴航,黄卫红,钱晓良,陆晓华.超临界水氧化法水处理技术进展[J].化工环保,2001,21(2):79-83. 被引量:31
  • 9Zhang Xiaogang,Gao Liang,Liu Zhimin,et al.Effect of size and polarity of solutes on partial molar volumes and intermolecular interaction in supercritical fluids[J].Journal of Supercritical Fluids,2002,23:233-241.
  • 10Jonson J W,Norton D.Critical phenomena in hydrothermal system: state,thermodynamic,electrostatic and transport properties of H2O in the critical region[J].Am J Sci,1991,291: 541-648.

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