摘要
使用积分反应器在孔砖型催化剂原型上研究了 CH_4、CO_2和水蒸汽催化反座。获得的宏观反应动力学模型为{R_(CH_4)=0.099exp(-50010/RT)P_(CH_4)^(3·31) P_(CO_2)^(-2·39)R_(CO_2)=0.22exp(-86503/RT)P_(CH_4)^(2·40) P_(CO_2)^(-1·69)(1-Q./K.)
An integral-mode reactor is used to study the reaction of Ch_4 with CO_2 and steam,over a perforated brick-shaped catalyst mass.The mac- roscopic kinetic models ard found as R_(CH_4)=0.099cxp(-50010/RT)P_(CH_4)^(3.31)P_(CO_2)^(-2.03) R_(CO_2)=0.22exp(-86503/RT)P_(CH_4)^(2.240)P_(CO_2)^(-1.66)(1-Q_P/K_P)