摘要
合成了一种新的手性β－二酮－（＋）－乙酰－ｄ－龙脑酰基甲烷［Ｈ（ａｃｍ）］，确证了结构，进一步将其制成Ｅｕ＋３络合物，并研究了手性位移效果．
A new chiral β-diketon (+) -acetyl--d--campholyl methene H (acm) has been found. Its structure has been identified by 1H NMR, IR and MS spectra and ensured by elementary analysis. The complex of H(acm) with Eu3+ is prepared and the chiral shift effectivity of this complex is studied.
基金
国家自然科学基金
关键词
二酮
铕
手性位移效果
chiral β-diketone
(+)-acetyl-d-campholyl methene
study of chiral shift effectivity
