摘要
以己二酸为原料,经历六步反应合成了标题化合物,手性相转移催化剂(3S,4S)—1—苄基—1—甲基—3,4—二羟基吡咯碘化铵在形成手性碳中心的关键步骤中起到了良好的促进作用。
Title compund have been synthesized from adipic acid (starting material ) in six steps, a chiral phase transfer catalyst (3s,4s)-1-benzyle-1-methyl-3,4 - pyrrolidindiol-onium iodide (PTC) was used to promote the iasymmetric reactions in the key steps of forming chiral centers
出处
《中国海洋药物》
CAS
CSCD
1994年第2期31-33,共3页
Chinese Journal of Marine Drugs
关键词
戊内酯
海藻抗生素
类似物
手性相转移
催化剂
valerolactone
marine antibiocic analoque
chiral phase transfer catalyst
