摘要
合成了三种锰（Ⅲ）（希夫碱配合物：Ｍｎ（Ｂｚａｃｅｎ）ＢＣｌＯ＿４（Ｂ为吡啶、哌嗪、Ｙ－甲基吡啶），其中Ｂｚａｃｅｎ￣２－为Ｎ，Ｎ’－二（苯甲酰丙酮缩）─乙二胺阴离子。用ＮＭＲ法测定了配合物在ＤＭＳＯ溶液中的有效进矩并对其电子光谱和红外光谱的吸收带进行了归属。
Three Manganese(Ⅲ)Schiff Base Complexes of Mn(bzacen)(B stands for pyridine,pyrazineand γ-Methyl pyridine respectively),where bzacen￣2- is the di-anion of bis (benzoylacetone)ethylenediimine,have been synthesized,By means of the NMR method,the magnetic susceptibility ofthe complexes has been determined in the DMSO solution. The bands of its electronic spoctra and thevibrations of IR spectra have been tentatively assigned.
出处
《浙江师大学报（自然科学版）》
CAS
1994年第1期54-56,共3页
Journal of Zhejiang Normal University(Natoral Sciences)
关键词
席夫碱
络合物
合成
锰
Manganese(Ⅲ)
Schiff Base Complex
