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天线若丹明染料分子内能量与电荷传递的研究 被引量:2

Studies on Intramolecular Energy Transfer and Charge Transfer in Trichromophoric Antenna Rhodamine Dyes
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摘要 The triplet lifetime of some trichromophoric antenna rhodamine dyes have been measured by nanosecond laser flash photolysis and phosphorescence decay method.The intramolecular triplet energy transfer and intramolecular charge transfer in these dyes have been discussed. These processes may affect the lasing efficiency as well as the emission wavelength of the antenna dyes. The experimental results support the existence folded conformation in the antenna rhodamine dyes linked with CH2-CH2. The triplet lifetime of some trichromophoric antenna rhodamine dyes have been measured by nanosecond laser flash photolysis and phosphorescence decay method.The intramolecular triplet energy transfer and intramolecular charge transfer in these dyes have been discussed. These processes may affect the lasing efficiency as well as the emission wavelength of the antenna dyes. The experimental results support the existence folded conformation in the antenna rhodamine dyes linked with CH2-CH2.
作者 田禾
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1994年第3期193-196,共4页 Acta Physico-Chimica Sinica
基金 国家自然科学基金
关键词 激光 染料 若丹明 电荷转移 三重态 Laser dyes,Energy transfer,Intramolecular charge transfer,Triplettriplet absorption,Triplet lifetime
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  • 1田禾,苏建华,陈孔常,张镇平,郭孟鑫.新型双发色团染料荧光光谱及其寿命的研究[J].感光科学与光化学,1996,14(4):355-359. 被引量:3
  • 2苏建华,华东理工大学学报,1996年,22卷,4期,422页
  • 3田禾,J Photochem & Photobiol A.Chem,1995年,91卷,125页
  • 4田禾,Dyes and Pigments,1994年,26卷,159页
  • 5田禾,Dyes and Pigments,1994年,26卷,167页

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