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甲醇制汽油(MTG)集总动力学模型 被引量:2

LUMPING KINETIC MODEL FOR METHANOL CONVERSION TO GASOLINE(MTG)
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摘要 用Sedran ̄[1]的模型,对甲醇在ZSM-5分子筛上转化制汽油过程进行了集总动力学研究。用单纯形法对实验数据进行回归分析,求出了动力学参数。将此动力学模型预测固定床反应结果,计算值与实测值相对平均误差小于20%。 The Lumping kinetic model for methanol conversion to gasoline over ZSM-5 zeolite was studied.The kinetic parameters were obtained by the re-gression of experimental data using simple method.The model was used to predict the reaction results of fixed-bed reactor and the average deviations of the calculated values from experimental data were less than 20%.
出处 《煤炭转化》 CAS CSCD 北大核心 1994年第2期14-19,共6页 Coal Conversion
关键词 甲醇 汽油 集总动力学 模型 沸石 methanol,gasoline,lumped kinetic model,zeolite ZSM-5
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同被引文献18

  • 1杨明平,罗娟.甲醇制低碳烯烃反应体系的热力学计算与分析[J].煤化工,2008,36(3):44-48. 被引量:8
  • 2姜玄珍,Howe,RF.在H-ZSM-5沸石上甲醇转化为汽油的初始产物分布[J].分子催化,1994,8(3):237-241. 被引量:1
  • 3齐国祯,谢在库,钟思青,张成芳,陈庆龄.甲醇制低碳烯烃(MTO)反应热力学研究[J].石油与天然气化工,2005,34(5):349-353. 被引量:26
  • 4于海卫,刘盛林,刘伟成,王清遐,徐龙伢.汽油中烯烃异构和芳构化偶合热力学分析[J].石油学报(石油加工),2007,23(2):51-56. 被引量:3
  • 5Zaidi H A, Pant K K. Catalytic conversion of methanol to gasoline range hydrocarbons [J]. Catal Today, 2004, 96:155-160.
  • 6Zeng D L, Yang J, Wang J Q, et al. Solid-state NMR studies of methanol-to-aromatics reaction over silver exchanged HZSM-5 zeolite[J].Microporous Mesoporous Mater,2007, 98: 214-219.
  • 7Bjorgen M, Svelle S, Joensen F,et al. Conversion of methanol to hydrocarbons over zeohte H-ZSM-5: On the origin of the olefinic species[J]J Catal, 2007,249:195-207.
  • 8Kanazirev V, Tsoncheva T. A study of the nonstationary character of the methanol to hydrocarbons conversion[J]. Can J Chem,1992,70:1997-2002.
  • 9Chang C D. A kinetic model for methanol conversion to hydroearbons[J].Chem Eng Sci,1980,35:619-622.
  • 10Sedran U, Mahay A, Delasa H I.Modelling methanol conversion to hydrocarbons: revision and testing of a simple kinetic model[J].Chem Eng Sci, 1990,45(5):1161-1165.

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