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计算光度法同时测定微量W和M_0的研究 被引量:1

Simaltaneous Spectrometric Determination of Tungsten and Molybdenum by the Calculated Method
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摘要 以钨、铜的PV-CTMAB为体系,在pH=5.5时,用多波长数据线性回归法同时测定微量的钨和钼。选择的波长区间为650~690nm,当钨和钼含量比率在1:3和6:1范围内,相对误差小于±8%. The linear regression method of multi-wavelength data was applied to the detemination of W and Mo in the ternary complexes of PV-CTMAB - W, Plus Mo system. The spectrophometric characteristie of the system,optimum conditions for the complex formation and effects of foreign ions were studied.The absorbances of the mixture contained W and Mo were measured at many wavelengths,and the data were treated by linear regression method to evaluate the coneentration of W and Mo.In the range from 650 um to 690 nm, the RSD(%) was less than 8% for microamOunts of W and Mo with eoneentration ratio from 1: 3 to 6: 1
出处 《河南大学学报(自然科学版)》 CAS 1994年第1期64-67,共4页 Journal of Henan University:Natural Science
关键词 分光光度法 测定 Molybdenum,Tungsten,linear regression,Simultaneous determination, Spectrophometry.
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