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高芳烃油填充镍系顺丁橡胶的性能 被引量:5

PROPERTIES OF HIGH AROMATIC OILS EXTENDED POLYBUTADIENE RUBBER WITH NICKEL CATALYST
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摘要 采用干法充油工艺制得了10种油品的充油镍系顺丁橡胶。试验结果表明,填充37.5份安庆石油化工总厂1#~4#高芳烃油及济南炼油厂三线抽出油的充油胶,ML为40~44;硫化胶的拉伸强度、定伸应力、扯断伸长率和硬度等基本力学性能均达到镍系充油胶技术指标;高芳烃含量较低的5#~7#油品充油胶门尼粘度和硫化胶强伸性能偏低;8#,9#油品因含有大量胶质,其充油胶表现出一些特殊性。表明填充油的性质对充油胶性能有明显影响。 Ten kinds of oil-extended polybutadiene rubber(OEBR)with nickel catalyst were prepared and their properties were investigated.The results indicated that when the OEBRs extended with 37.5phr of 1 ̄#~4 ̄# high aromatic oils,ML was 40~44,the tensile strength,300% modulus,elongation at break and hardness of the vulcanizates could reach the technical standard of oil-extended NiBR.The Mooney viscosity and the strength of the vulcanized OEBRs extended with 5 ̄#~7 ̄#oils were lower,and the OEBRs extented with 8 ̄#and 9 ̄#oils showed special characteristics because of their high gel content.The properties of extender oils had obvious influence on the performance of OEBR.
出处 《合成橡胶工业》 CAS CSCD 北大核心 1994年第6期362-364,共3页 China Synthetic Rubber Industry
关键词 顺丁橡胶 填充油 充油橡胶 镍系 芳烃油 cis-1,4-polybutadiene rubber extended oil oil-extended rubber vulcanizate mechanical property processability
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参考文献3

  • 1宋宏,郭春玲,王金良.镍系充油顺丁橡胶的结构及某炭黑混炼胶的流变行为[J]合成橡胶工业,1985(03).
  • 2乔三阳.充油顺丁胶填充油的选择[J]合成橡胶工业,1983(05).
  • 3张新惠,刘亚东,陈启儒,徐敬梅.油品性质对稀土顺丁充油橡胶性能的影响[J]合成橡胶工业,1983(02).

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