摘要
采用干法充油工艺制得了10种油品的充油镍系顺丁橡胶。试验结果表明,填充37.5份安庆石油化工总厂1#~4#高芳烃油及济南炼油厂三线抽出油的充油胶,ML为40~44;硫化胶的拉伸强度、定伸应力、扯断伸长率和硬度等基本力学性能均达到镍系充油胶技术指标;高芳烃含量较低的5#~7#油品充油胶门尼粘度和硫化胶强伸性能偏低;8#,9#油品因含有大量胶质,其充油胶表现出一些特殊性。表明填充油的性质对充油胶性能有明显影响。
Ten kinds of oil-extended polybutadiene rubber(OEBR)with nickel catalyst were prepared and their properties were investigated.The results indicated that when the OEBRs extended with 37.5phr of 1 ̄#~4 ̄# high aromatic oils,ML was 40~44,the tensile strength,300% modulus,elongation at break and hardness of the vulcanizates could reach the technical standard of oil-extended NiBR.The Mooney viscosity and the strength of the vulcanized OEBRs extended with 5 ̄#~7 ̄#oils were lower,and the OEBRs extented with 8 ̄#and 9 ̄#oils showed special characteristics because of their high gel content.The properties of extender oils had obvious influence on the performance of OEBR.
出处
《合成橡胶工业》
CAS
CSCD
北大核心
1994年第6期362-364,共3页
China Synthetic Rubber Industry
关键词
顺丁橡胶
填充油
充油橡胶
镍系
芳烃油
cis-1,4-polybutadiene rubber
extended oil
oil-extended rubber
vulcanizate
mechanical property
processability