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α－FeOOH在含氯离子电解质溶液中的界面模型 被引量：1

THE MODEL OF THE α-FERRIC OXYHYDROXIDE/AQUEOUS ELECTROLYTE WITH CHLORINE IONS INTERFACE
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摘要 根据双电层由固体表面、内外Ｈｅｌｍｈｏｔｚ层组成，且表面电荷的分布由表面电离、表面配位决定的理论，本文建立了α－ＦｅＯＯＨ／ＮａＣｌ胶体悬浮液的界面模型，导出了与双电层内电荷及电势分布有关的表面电离、表面配位平衡常数的表达式。 Interfacial Model of α-FeOOH, the important product of coorrosion,/NaCl aq. has been set up in terms of a three-planes theory of electric double layer.Then, the main objective of this study is a detailed deduction of the quantitative expressions for surface ionisation and surface complexation constants.
作者 沈致隆 张轶 仇华栋
机构地区 北京轻工业学院化学工程系
出处 《北京轻工业学院学报》 1994年第1期14-20,共7页 Journal of Beijing Institute of Light Industry
关键词 Α-FEOOH 氯离子 电解质溶液 界面模型 surface site, surface ionisation, surface complexation, ion-pairs at charged surface sites
分类号 O646.1 [理学—物理化学] O648.11 [理学—物理化学]
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  • 9Bousselmi L, Fiaud C, Tribollet B, et al. Impedance spectroscopic study of a steel electrode in condition of scaling and corrosion in terphase model[J]. Electroehim. Acta, 1999, 44:4357-4363.
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北京轻工业学院学报
1994年 第1期

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