摘要
本文以电导法测定了四丁基溴化铵合成反应体系的浓度和时间的关系;确定了此反应为二级反应;求出了不同温度下的反应速率常数、活化能、指前因子以及活化熵变;初步拟定了反应机理.
The relation concentration and time of system TBAB synthetic reaction is determi-nated by electrical conductance in this paper.The reaction is second-order and activation ener-gy,factor before exponent,activation entropy,reaction speed constant in different tempera-tures are given. The reaction mechanism have drawn up preliminary.[
出处
《北京联合大学学报》
CAS
1994年第4期31-34,共4页
Journal of Beijing Union University
关键词
四丁基溴化铵
电导
反应动力学
tetrabutylaminebromide
electrical conductance
kinetics of reaction