摘要
本文合成了Ｎ－萘基甲基丙烯酰胺（ａ－ＨＭＡ）与甲基丙烯酸甲酯（ＭＭＡ）的本体共聚物。ａ－ＨＭＡ的含量分别为３％、５％、８％、１０％、１５％、２０％、２５％、３０％。共聚体的硬度随着共聚体中ａ－ＨＭＡ的含量增高而提高；但透光率却随着ａ－ＨＭＡ含量增高而下降；软化温度变化不大。共聚体比聚甲基丙烯酸甲酯具有更好的耐溶剂性能。ａ－ＨＭＡ－－ｃｏ－ＭＭＡ共聚物较甲基丙烯酰胺（ＭＡＤ）－甲基丙烯酸甲酯共聚物（ＭＭＡ）具有更好的耐水性。
Bulk copolymers of a-Naphthyl methacrylamide( a-HMA) with Methyl Methacry- late(MMA) have been prepared. It has been found that the title copolymers are moreheat- resistant than polymethylmethacrylate(PMMA). When the alnount of the amidechanges from 5%to 10%the hardness of the copolymers increases from 25.0kg/mm￣2 to29. 0kg/mm￣2 but the transparency of the copolymers decreases from 91%to 77%。 Thea-HMA-co-MMA copolymers have better solvent resistance properties than PMMA. Incomparison with MAD-co-MMA copolymers, the a-HMA-co-MMA copolymers havebetter water-resistance.
出处
《北京大学学报（自然科学版）》
CSCD
北大核心
1994年第1期122-128,共7页
Acta Scientiarum Naturalium Universitatis Pekinensis
关键词
共聚物
共聚反应
α-HMA
MMA
a-Naphthylmethacrylamide
Copolymer
Copolymerization
Copolylymerof PMMA
