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甲醇氧化重整制氢反应动力学的研究 被引量：6

Kinetics of the partial oxidation of methanol
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摘要 在Cr Zn氧化物催化剂上系统地考察了不同反应温度下W/FCH3OH对甲醇总包转化率、水蒸汽重整转化率以及分解转化率的影响 ,由准质量作用定律得出了反应速率表达式 ,并根据实验结果求解了动力学参数值。F 检验表明本动力学模型是可行的。 The kinetics of the partial oxidation (POX) of methanol was investigated on the Cr Zn metal oxide catalyst developed in authors laboratory, and the power law rate model for methanol steam reforming and methanol decomposing, the two rate determination step in POX, was obtained. F-test showed that the two expressions were suitable to the criteria of validation in chemical engineering.
作者 亓爱笃 洪学伦 王树东 付桂芝 吴迪镛
机构地区 中国科学院大连化学物理研究所
出处 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 2000年第4期18-21,共4页 Natural Gas Chemical Industry
基金 科技部"九五"攻关项目
关键词 甲醇 氢气 氧化重整 动力学 methanol hydrogen partial oxidation kinetics
分类号 TQ02 [化学工程]
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参考文献5

  • 1　L Alejo，R Lago，et al．，Partial oxidation of methanol to produce hydrogenover Cu-Zn-based catalysts [J]．Applied Catalysis A:General,1997,162:281－297．
  • 2　C J Jiang，D L Trimm,et al．，Kinetic mechanism for the reaction betweenmethanol and water over a Cu-ZnO-Al2O3 catalyst[J]． AppliedCatalysis A，1993，97:145．
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  • 5　B A Peppley，J C Amphlett,et al．，Methanol-steam reforming on Cu/ZnO/Al2O3catalysts．Part 2．A comprehensive kinetic model[J]．Applied CatalysisA:General,1999,179:31－49．

同被引文献41

  • 1刘娜,王树东,袁中山,张纯希,王淑娟,李德意,付桂芝.甲醇自热重整制氢整体催化剂的制备[J].化工学报,2004,55(S1):90-94. 被引量：6
  • 2王锋,李隆键,崔文智,辛明道.微反应器中甲醇-水蒸气重整制氢三维模拟[J].重庆大学学报（自然科学版）,2007,30(2):26-29. 被引量：5
  • 3Vasudeva K, Mitra N, Umansankar P, et al. Steam reforming of ethanol for hydrogen production:thermodynamic analysis [J]. Int J Hydrogen Energy,1996, 21(1): 13-18.
  • 4Klouz V, Fierro V, Denton P. Ethanol reforming for hydrogen production in a hybrid electric vehicle: process optimization[J]. J Power Source, 2002, 105: 26-34.
  • 5Fierro V, Klouz V, Akdim O, et al. Oxidative reforming of biomass derived ethanol for hydrogen production in fuel cell applications[J] . Catal Today,2002, 75= 14-144.
  • 6Sernelsberger T A, Brown L F, Borup R L, et al.Equilibrium products from auto-thermal processes for generating hydrogen-rich fuel-call feeds [J ] . Int J Hydrogen Energy, 2004, 29: 1047-1064.
  • 7Vonka P, Leimer J. Calculation of chemical equilibria in heterogeneous multicomponent systems [ J ] . Calphad,1995, 19(1): 25-36.
  • 8Chan S H, Wang H M. Thermodynamic and kinetic modelling of an auto-thermal methanol reformer [J ] . J Power Sources, 2004, 16: 8-15.
  • 9Haines J R, Tsai C C. Graphite Sublimation Tests for the Muon Collider/Neutrino Factory Target Development Program[Z]. ORNL/TM, 2002(2), 27.
  • 10Reid R C, Prausnitz J M, Poling B E. The Properties of Gases and Liquids [ M] . 4th Edition, New York:McGraw-Hill Book Company, 1987, 665-677.

引证文献6

二级引证文献21

天然气化工—C1化学与化工
2000年 第4期

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