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稻草的氧碱法制浆(3)──Na_2CO_3和NaOH在制浆过程中的作用 被引量:1

Alkali-Oxygen Pulping of Rice Straw(3)-Role of Na_2CO_3 and NaOH in the Pulping
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摘要 用Na2CO3和NaOH于稻草的碱浸渍和氧气蒸煮的两段氧碱制浆过程的研究表明,同样的用碱量时,Na2CO3的氧碱制浆效果明显不如NaOH。即便是大过量的Na2CO3也难以活化氧化性质低的木素,导致氧脱木素效率低。然而Na2CO3在一定的NaOH存在下,除了氧化效率不如单用NaOH时的情形之外,所得纸浆的强度性能指标与用NaOH的纸浆差别不大。它对辅助氧碱制浆反应的作用明显。从氧碱制浆效率及经济方面考虑,应使用纯度较高的NaOH于氧碱制浆当中。 The role of Na2CO3 and NaOH were compared in a two-stage pulping process (alkali soakingand oxygen delignification) of rice straw. Pulping with Na2CO3 gave inferior results compared with that fromNaOH. This is particular true when alkali soaking is to be followde by oxygen delignification. It has beendemonstrated that any Na2CO3 present in the NaOH pulping liquor will tend to lower the resultant pulpbrightness, even though the physical strengths of the pulp are not much affected. It is important therefore,that in the alkali oxygen pulping process, NaOH used must be as pure as possible.
出处 《中国造纸学报》 CAS CSCD 北大核心 1997年第B12期6-10,共5页 Transactions of China Pulp and Paper
关键词 氧碱制浆 制浆过程 碱法制浆 NA2CO3 纸浆 蒸煮 用碱量 OH 浸渍 纯度 allkali-oxygen pulping, rice straw, alkali soaking, oxygen delignification
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  • 1陈克利,林治助.稻草的氧碱法制浆(1)──中浓法制浆与高浓法制浆的比较[J].中国造纸学报,1996,11(C00):8-14. 被引量:9
  • 2K. Kratzl,P. Claus,W. Lonsky,J. S. Gratzl. Model studies on reactions occurring in oxidations of lignin with molecular oxygen in Alkaline Media[J] 1974,Wood Science and Technology(1):35~49
  • 3K. Kratzl,W. Sch?fer,P. Claus,J. Gratzl,P. Schilling. Zur Oxydation von14C-markierten Phenolen (Ligninmodellen) in w??rig-alkalischer L?sung mit Sauerstoff[J] 1967,Monatshefte für Chemie(3):891~904

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