摘要
研究了用正-丁基辛基亚砜萃取、S-丁基异硫脲盐反萃金(Ⅲ)的行为.实验结果表明萃合物的组成为H_3O(n-BOSO)_3AuCl_4,反萃金(Ⅲ)是离子交换机理,金(Ⅲ)萃合物用元素分析、热分析、摩尔电导、UV和IR光谱进行了表征。
In this paper, the behavior for extraction and back-extraction of gold (Ⅲ) with n-butyloctyl sulfoxide and s-n-butylisothiouronium have been investigated, respectively. Experimental results showed that the composition of extraction complex is H3O(n-BOSO)3AuCl4 and back-extraction of gold(Ⅲ) is ion exchange machanism. The extraction complex of gold(Ⅲ) has been characterized by element analysis, thermal analysis, molar conductance, UV and IR spectra.
出处
《云南大学学报（自然科学版）》
CAS
CSCD
1993年第2期109-113,共5页
Journal of Yunnan University(Natural Sciences Edition)
关键词
不对称
亚砜
烷基异硫脲盐
金
Unsymmetrical sulfoxide, s-Alkylisothiouronium, Gold(Ⅲ), Extrac-tion complex
