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贮氢合金高倍率放电性能的研究 被引量:1

The research on high-rate discharge ability of hydrogen storage alloy
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摘要 利用正交实验研究了贮氢合金的组成及各元素的含量对高倍率放电性能的影响,得出最佳配比为La0 71Ce0 1Pr0 09Nd0 1Ni4 4Co0 2Mn0 2Al0 2。随着La含量在一定范围内的增加或者Co和Al含量的减少,合金高倍率放电能力会得到改善,Mn含量在一定范围内变化对高倍率放电性能的影响不大。研究了粒度对高倍率放电性能的影响,粒度为200~300目最佳。 The effect of the composition of hydrogen storage alloy and the content of its elements on high-rate discharge ability were studied by orthogonal experiment.The optimized composition was La_(0.71)Ce_(0.1)Pr_(0.09)Nd_(0.1)Ni_(4.4)Co_(0.2)Mn_(0.2)Al_(0.2).The high-rate discharge ability of alloy electrodes were improved with the increase of La in some area and the decrease of Co and Al.The change of Mn content had less effect on it.The effect of graininess on high-rate discharge ability was studied, the proper granularity was in 200~300 mesh.
出处 《电池》 CAS CSCD 北大核心 2004年第6期432-433,共2页 Battery Bimonthly
关键词 贮氢合金 电化学性能 放电容量 高倍率放电性能 hydrogen storage alloy electrochemical properties discharge capacity high-rate discharge ability
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  • 1Liquan L, Akiyama T, Kabutomori T,et al. In situ X-ray diffraction study of the hydriding combustion synthesis of Mg2NiH4[J]. J Alloys Compounds, 1998,281(2): 175 - 180.
  • 2Ise T, Murata T, Hirota Y, et al. The effect of particle size on the electrochemical properties of hydrogen absorbing alloy electrodes[J]. J Alloys and Compounds, 1999,298( 1 - 2) :310 - 318.
  • 3HU Zi-long(胡子龙).贮氢材料[M].Beijing(北京):Chemical Industry Press(化学工业出版社),2002.287-289.
  • 4Kazuhide T, Yoshisada K, Masaki F, et al. Improvement of hydrogen storage ProPerties of melt-spun Mg-Ni-RE alloys by nanocrystallization[J]. J Alloys and Compounds, 1999,293 - 295:521 - 525.

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